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A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane
[Image: see text] Using solid-state molecular organometallic (SMOM) techniques, in particular solid/gas single-crystal to single-crystal reactivity, a series of σ-alkane complexes of the general formula [Rh(Cy(2)PCH(2)CH(2)PCy(2))(η(n):η(m)-alkane)][BAr(F)(4)] have been prepared (alkane = propane, 2...
Guardat en:
| Publicat a: | J Am Chem Soc |
|---|---|
| Autors principals: | , , , , , , , , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical
Society
2021
|
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8154534/ https://ncbi.nlm.nih.gov/pubmed/33769815 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c00738 |
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