A Series of Crystallographically Characterized Linear and Branched σ-Alkane Complexes of Rhodium: From Propane to 3-Methylpentane

[Image: see text] Using solid-state molecular organometallic (SMOM) techniques, in particular solid/gas single-crystal to single-crystal reactivity, a series of σ-alkane complexes of the general formula [Rh(Cy(2)PCH(2)CH(2)PCy(2))(η(n):η(m)-alkane)][BAr(F)(4)] have been prepared (alkane = propane, 2...

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Pubblicato in:J Am Chem Soc
Autori principali: Bukvic, Alexander J., Burnage, Arron L., Tizzard, Graham J., Martínez-Martínez, Antonio J., McKay, Alasdair I., Rees, Nicholas H., Tegner, Bengt E., Krämer, Tobias, Fish, Heather, Warren, Mark R., Coles, Simon J., Macgregor, Stuart A., Weller, Andrew S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2021
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8154534/
https://ncbi.nlm.nih.gov/pubmed/33769815
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c00738
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