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Structures and Reactivities of Sodiated Evans Enolates: Role of Solvation and Mixed Aggregation on the Stereochemistry and Mechanism of Alkylations
Oxazolidinone-based sodiated enolates (Evans enolates) were generated using sodium diisopropylamide (NaDA) or sodium hexamethyldisilazide (NaHMDS) in the presence of N,N,N′,N′-tetramethylethylenediamine (TMEDA), (R,R)-trans-N,N,N′,N′-tetramethylcyclohexanediamine [(R,R)-TMCDA], or (S,S)-TMCDA. (13)C...
Na minha lista:
| Foilsithe in: | J Am Chem Soc |
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| Main Authors: | , |
| Formáid: | Artigo |
| Teanga: | Inglês |
| Foilsithe: |
2018
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| Ábhair: | |
| Rochtain Ar Líne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7185956/ https://ncbi.nlm.nih.gov/pubmed/30462500 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b10364 |
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