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Evans Enolates: Structures and Mechanisms Underlying the Aldol Addition of Oxazolidinone-Derived Boron Enolates
The soft enolization of an acylated oxazolidinone using di-n-butylboron triflate (n-Bu(2)BOTf) and trialkylamines and subsequent aldol addition was probed structurally and mechanistically using a combination of IR and NMR spectroscopies. None of the species along the reaction coordinate shows a penc...
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| Pubblicato in: | J Org Chem |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2017
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6097535/ https://ncbi.nlm.nih.gov/pubmed/28686020 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.7b01365 |
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