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Wittig Rearrangements of Boron-Based Oxazolidinone Enolates
[2,3]-Sigmatropic rearrangements (Wittig rearrangements) of α-alkoxy oxazolidinone enolates are described. Whereas alkali metal enolates fail owing to facile deacylation, boron enolates generated from di-n-butylboron triflate and triethylamine rearranged in good yields and high selectivities with ex...
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| Publié dans: | J Org Chem |
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| Auteurs principaux: | , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2019
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7050190/ https://ncbi.nlm.nih.gov/pubmed/31414796 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b01426 |
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