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Wittig Rearrangements of Boron-Based Oxazolidinone Enolates

[2,3]-Sigmatropic rearrangements (Wittig rearrangements) of α-alkoxy oxazolidinone enolates are described. Whereas alkali metal enolates fail owing to facile deacylation, boron enolates generated from di-n-butylboron triflate and triethylamine rearranged in good yields and high selectivities with ex...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Zhang, Zirong, Collum, David B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7050190/
https://ncbi.nlm.nih.gov/pubmed/31414796
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b01426
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