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Lithium Enolates Derived from Pyroglutaminol: Aggregation, Solvation, and Atropisomerism

Lithium enolates derived from protected pyroglutaminols were characterized by using (6)Li, (13)C, and (19)F NMR spectroscopies in conjunction with the method of continuous variation. A mixture of tetrasolvated dimers and tetrasolvated tetramers in proportions depend on the steric demands of the hemi...

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Detalhes bibliográficos
Publicado no:J Org Chem
Main Authors: Houghton, Michael J., Biok, Naomi A., Huck, Christopher J., Algera, Russell F., Keresztes, Ivan, Wright, Stephen W., Collum, David B.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5245164/
https://ncbi.nlm.nih.gov/pubmed/27035057
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b00459
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