Pseudophedrine-Derived Myers Enolates: Structures and Influence of Lithium Chloride on Reactivity and Mechanism

The structures and reactivities of pseudoephedrine-derived dianionic Myers enolates are examined. A combination of NMR and IR spectroscopic, crystallographic, and computational data reveal that the homoaggregated dianions form octalithiated tetramers displaying S(4)-symmetric Li(8)O(8) cores and ove...

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Udgivet i:J Am Chem Soc
Main Authors: Zhou, Yuhui, Jermaks, Janis, Keresztes, Ivan, MacMillan, Samantha N., Collum, David B.
Format: Artigo
Sprog:Inglês
Udgivet: 2019
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Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC7079698/
https://ncbi.nlm.nih.gov/pubmed/30896939
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00328
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