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Lithium Enolates Derived from Weinreb Amides: Insights into Five-Membered Chelate Rings
Enolization of O-methyl hydroxamic acids (Weinreb amides) in tetrahydrofuran solution with lithium diisopropylamide affords predominantly tetrameric enolates. Aryl substituents on the enolates promote deaggregation. The aggregation states are assigned by using the method of continuous variation in c...
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| Pubblicato in: | J Org Chem |
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| Autori principali: | , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2016
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5261255/ https://ncbi.nlm.nih.gov/pubmed/27749060 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.6b02067 |
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