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Bifunctional Phosphine Ligand-Enabled Gold-Catalyzed Isomerizations of Alkynamides: Rapid Access to Electron-Rich 2-Aminofurans and Their Diels-Alder Reactions
By using biphenyl-2-ylphosphines functionalized with a remote tertiary amino group as ligand, readily available acetylenic amides are directly converted into 2-aminofurans devoid of any electron-withdrawing and hence deactivating/stabilizing substituents. These highly electron-rich furans have rarel...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2019
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7173349/ https://ncbi.nlm.nih.gov/pubmed/31531919 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201908598 |
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