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Quantum Chemical Investigation of Dimerization in the Schlenk Equilibrium of Thiophene Grignard Reagents
The Schlenk equilibrium of Grignard reagents describes the intricate relationships between monomers, aggregates, and exchange products. The core step of the Schlenk equilibrium, formally 2RMgX ⇌ R(2)Mg + MgX(2), has been subject to computational studies of simple methyl Grignards and NMR determinati...
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| Vydáno v: | J Phys Chem A |
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| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2020
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7170039/ https://ncbi.nlm.nih.gov/pubmed/32011885 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.9b09985 |
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