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Investigation of Grignard Reagent as an Advanced Base for Aza-Claisen Rearrangement
Employing iPrMgCl as an advanced base instead of lithium hexamethyldisilazane (LHMDS) resulted in dramatic improvements in aza-Claisen rearrangement. This advance is considered responsible for the increased bulkiness of the alkoxide moiety (including magnesium cation and ligands), followed by a resu...
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| Publicado no: | Molecules |
|---|---|
| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
MDPI
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6943632/ https://ncbi.nlm.nih.gov/pubmed/31888158 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/molecules24244597 |
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