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Chiral piperidines from acyclic amines via enantioselective, radical-mediated δ C-H cyanation
Piperidines are the most prevalent heterocycle found in medicines. Yet, while they are often chiral, there remain no robust methods for their asymmetric syntheses. To solve this challenge, we have interrupted the century-old Hofmann-Löffler-Freytag (HLF) reaction to afford this privileged heterocycl...
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| Yayımlandı: | Chem |
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| Asıl Yazarlar: | , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
2019
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| Konular: | |
| Online Erişim: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7158869/ https://ncbi.nlm.nih.gov/pubmed/32296736 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.chempr.2019.09.010 |
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