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δ C–H (hetero)arylation via Cu-catalyzed radical relay
A Cu-catalyzed strategy has been developed that harnesses a radical relay mechanism to intercept a distal C-centered radical for C–C bond formation. This approach enables selective δ C–H (hetero)arylation of sulfonamides via intramolecular hydrogen atom transfer (HAT) by an N-centered radical. The r...
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| Udgivet i: | Chem Sci |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
Royal Society of Chemistry
2018
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6349054/ https://ncbi.nlm.nih.gov/pubmed/30774920 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04366c |
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