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δ C–H (hetero)arylation via Cu-catalyzed radical relay

A Cu-catalyzed strategy has been developed that harnesses a radical relay mechanism to intercept a distal C-centered radical for C–C bond formation. This approach enables selective δ C–H (hetero)arylation of sulfonamides via intramolecular hydrogen atom transfer (HAT) by an N-centered radical. The r...

詳細記述

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書誌詳細
出版年:Chem Sci
主要な著者: Zhang, Zuxiao, Stateman, Leah M., Nagib, David A.
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC6349054/
https://ncbi.nlm.nih.gov/pubmed/30774920
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04366c
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