Llwytho...
The 9H‐9‐Borafluorene Dianion: A Surrogate for Elusive Diarylboryl Anion Nucleophiles
Double reduction of the THF adduct of 9H‐9‐borafluorene (1⋅THF) with excess alkali metal affords the dianion salts M(2)[1] in essentially quantitative yields (M=Li–K). Even though the added charge is stabilized through π delocalization, [1](2−) acts as a formal boron nucleophile toward organoboron (...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Angew Chem Int Ed Engl |
|---|---|
| Prif Awduron: | , , , , , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
John Wiley and Sons Inc.
2020
|
| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7155136/ https://ncbi.nlm.nih.gov/pubmed/31834978 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201914219 |
| Tagiau: |
Ychwanegu Tag
Dim Tagiau, Byddwch y cyntaf i dagio'r cofnod hwn!
|