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B−B Bond Nucleophilicity in a Tetraaryl μ‐Hydridodiborane(4) Anion
The tetraaryl μ‐hydridodiborane(4) anion [2H](−) possesses nucleophilic B−B and B−H bonds. Treatment of K[2H] with the electrophilic 9‐H‐9‐borafluorene (HBFlu) furnishes the B(3) cluster K[3], with a triangular boron core linked through two BHB two‐electron, three‐center bonds and one electron‐preci...
Gorde:
| Argitaratua izan da: | Angew Chem Int Ed Engl |
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| Egile Nagusiak: | , , , |
| Formatua: | Artigo |
| Hizkuntza: | Inglês |
| Argitaratua: |
John Wiley and Sons Inc.
2020
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| Gaiak: | |
| Sarrera elektronikoa: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7317828/ https://ncbi.nlm.nih.gov/pubmed/32058652 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202000292 |
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