Building up Strain in One Step: Synthesis of an Edge‐Fused Double Silacyclobutene from an Extensively Trichlorosilylated Butadiene Dianion

The exhaustive trichlorosilylation of hexachloro‐1,3‐butadiene was achieved in one step by using a mixture of Si(2)Cl(6) and [nBu(4)N]Cl (7:2 equiv) as the silylation reagent. The corresponding butadiene dianion salt [nBu(4)N](2)[1] was isolated in 36 % yield after recrystallization. The negative ch...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Georg, Isabelle, Bursch, Markus, Stückrath, Julius B., Alig, Edith, Bolte, Michael, Lerner, Hans‐Wolfram, Grimme, Stefan, Wagner, Matthias
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
Research Articles
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7540532/
https://ncbi.nlm.nih.gov/pubmed/32484309
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202006463
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