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A Spherically Shielded Triphenylamine and Its Persistent Radical Cation
This work reports the design and synthesis of a sterically protected triphenylamine scaffold which undergoes one‐electron oxidation to form an amine‐centered radical cation of remarkable stability. Several structural adjustments were made to tame the inherent reactivity of the radical cation. First,...
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| Veröffentlicht in: | Chemistry |
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| Hauptverfasser: | , , , , , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
John Wiley and Sons Inc.
2020
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7154785/ https://ncbi.nlm.nih.gov/pubmed/31970834 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202000355 |
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