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Enhancement of dye regeneration kinetics in dichromophoric porphyrin–carbazole triphenylamine dyes influenced by more exposed radical cation orbitals

Reduction kinetics of oxidized dyes absorbed on semiconductor surfaces and immersed in redox active electrolytes has been mainly modeled based on the free energy difference between the oxidation potential of the dye and the redox potential of the electrolyte. Only a few mechanisms have been demonstr...

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Pubblicato in:Chem Sci
Autori principali: Zhao, Long, Wagner, Pawel, Barnsley, Jonathan E., Clarke, Tracey M., Gordon, Keith C., Mori, Shogo, Mozer, Attila J.
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2016
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC6007200/
https://ncbi.nlm.nih.gov/pubmed/29997843
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc00429f
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