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UV-irradiation of self-assembled triphenylamines affords persistent and regenerable radicals

UV-irradiation of assembled urea-tethered triphenylamine dimers results in the formation of persistent radicals, whereas radicals generated in solution are reactive and quickly degrade. In the solid-state, high quantities of radicals (approximately 1 in 150 molecules) are formed with a half-life of...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Sindt, Ammon J., DeHaven, Baillie A., McEachern, David F., Dissanayake, D. M. M. Mevan, Smith, Mark D., Vannucci, Aaron K., Shimizu, Linda S.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6419929/
https://ncbi.nlm.nih.gov/pubmed/30996983
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc04607g
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