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The Reduction Potentials of P450 Compounds I and II: Insight into the Thermodynamics of C-H Bond Activation.
We present a mixed experimental/theoretical determination of the bond strengths and redox potentials that define the ground state thermodynamics for C-H bond activation in cytochrome P450 catalysis. Using redox titrations with [Ir(IV)Cl(6)](2−) we have determined the compound II/ferric (or Fe(IV)OH/...
Guardat en:
| Publicat a: | J Am Chem Soc |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2019
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7104868/ https://ncbi.nlm.nih.gov/pubmed/30892878 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b00242 |
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