Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes

The steric and electronic properties of aryl substituents in monoaryl borohydrides (Li[ArBH(3)]) and dihydroboranes were systematically varied and their reactions with [Ru(PCy(3))(2)HCl(H(2))] (Cy: cyclohexyl) were studied, resulting in bis(σ)‐borane or terminal borylene complexes of ruthenium. Thes...

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Pubblicato in:Chemistry
Autori principali: Lenczyk, Carsten, Roy, Dipak Kumar, Nitsch, Jörn, Radacki, Krzysztof, Rauch, Florian, Dewhurst, Rian D., Bickelhaupt, F. Matthias, Marder, Todd B., Braunschweig, Holger
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7079023/
https://ncbi.nlm.nih.gov/pubmed/31433081
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201902890
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