Toward Transition‐Metal‐Templated Construction of Arylated B(4) Chains by Dihydroborane Dehydrocoupling

The reactivity of a diruthenium tetrahydride complex towards three selected dihydroboranes was investigated. The use of [DurBH(2)] (Dur=2,3,5,6‐Me(4)C(6)H) and [(Me(3)Si)(2)NBH(2)] led to the formation of bridging borylene complexes of the form [(Cp*RuH)(2)BR] (Cp*=C(5)Me(5); 1 a: R=Dur; 1 b: R=N(Si...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Lenczyk, Carsten, Roy, Dipak Kumar, Oberdorf, Kai, Nitsch, Jörn, Dewhurst, Rian D., Radacki, Krzysztof, Halet, Jean‐François, Marder, Todd B., Bickelhaupt, Matthias, Braunschweig, Holger
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2019
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6972581/
https://ncbi.nlm.nih.gov/pubmed/31663648
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904772
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