Synthesis of Highly Fluorinated Arene Complexes of [Rh(Chelating Phosphine)](+) Cations, and their use in Synthesis and Catalysis

The synthesis of rhodium complexes with weakly binding highly fluorinated benzene ligands is described: 1,2,3‐F(3)C(6)H(3), 1,2,3,4‐F(4)C(6)H(2) and 1,2,3,4,5‐F(5)C(6)H are shown to bind with cationic [Rh(Cy(2)P(CH(2))(x)PCy(2))](+) fragments (x=1, 2). Their structures and reactivity with alkenes, a...

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Publicado no:Chemistry
Main Authors: McKay, Alasdair I., Barwick‐Silk, James, Savage, Max, Willis, Michael C., Weller, Andrew S.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2020
Assuntos:
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7078928/
https://ncbi.nlm.nih.gov/pubmed/31749160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201904668
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