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Kinetic Resolution via Rh-Catalyzed C–C Activation of Cyclobutanones at Room Temperature
Herein we describe the development of a highly selective kinetic resolution of cyclobutanones via a Rh-catalyzed “cut-and-sew” reaction with selectivity factor up to 785. This reaction takes place at room temperature with excellent efficiency. Various trans-5,6-fused bicycles and C2-substituted cycl...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7075347/ https://ncbi.nlm.nih.gov/pubmed/31568718 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b09344 |
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