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Kinetic Resolution of Benzylamines via Palladium(II)-Catalyzed C–H Cross-Coupling
A Pd(II)-catalyzed enantioselective C–H cross-coupling of benzylamines via kinetic resolution has been achieved using chiral mono-N-protected α-amino-O-methylhydroxamic acid (MPAHA) ligands. Both chiral benzylamines and ortho-arylated benzylamines are obtained in high enantiomeric purity. The use of...
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| Publicat a: | J Am Chem Soc |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2016
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5516893/ https://ncbi.nlm.nih.gov/pubmed/27249208 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b04660 |
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