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Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin

Progress toward the cyclobutane core of bielshowskysin is reported. The core was thought to arise from a cyclopropane intermediate via a furan-mediated cyclopropane fragmentation, followed by a 1,4-Michael addition. The synthesis of the cyclopropane intermediate utilizes a Suzuki coupling reaction,...

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Detalhes bibliográficos
Main Authors: Meyer, Michael E., Phillips, John H., Ferreira, Eric M., Stoltz, Brian M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2013
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3728638/
https://ncbi.nlm.nih.gov/pubmed/23913988
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2013.02.034
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