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A Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex
In recent years, a wide array of methods for achieving nickel-catalyzed substitution reactions of alkyl electrophiles by organometallic nucleophiles, including enantioconvergent processes, have been described; on the other hand, experiment-focused mechanistic studies of such couplings have been comp...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2019
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7075318/ https://ncbi.nlm.nih.gov/pubmed/31502449 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b08185 |
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