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Development of copper-catalyzed enantioselective decarboxylative aldolization for the preparation of perfluorinated 1,3,5-triols featuring supramolecular recognition properties

Fluorine is able to confer unique properties to organic molecules but the scarcity of natural organofluorine sources renders the development of new synthetic methods highly desirable. Using a chiral BOX/Cu combination, enantioselective decarboxylative aldolization of perfluorinated aldehydes has bee...

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Detalles Bibliográficos
Publicado en:Chem Sci
Main Authors: Sperandio, Céline, Rodriguez, Jean, Quintard, Adrien
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC7069514/
https://ncbi.nlm.nih.gov/pubmed/32206281
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc05196a
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