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Oxidation of an indole substrate by porphyrin iron(III) superoxide: Relevance to indoleamine and tryptophan 2,3-dioxygenases
Reaction of Fe(III)(O(2)(•−))(TPP) with 2,3-dimethylindole at −40 °C gives the ring-opened, dioxygenated N-(2-acetyl-phenyl)-acetamide product. The reaction was monitored in situ by low-temperature UV-Vis and (1)H NMR spectroscopies. This work demonstrates that a discrete iron(III)(superoxo) porphyr...
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| Udgivet i: | Chem Commun (Camb) |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2020
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7065957/ https://ncbi.nlm.nih.gov/pubmed/32052805 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc10019a |
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