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1,2-(Bis)trifluoromethylation of Alkynes: A One-Step Reaction to Install an Underutilized Functional Group

Modifying the electronic properties of olefins represents the quintessential approach to tuning alkene reactivity. In this context, the exploration of trifluoromethyl groups as divergent electronic modifiers has not been considered. Here, we describe a copper-mediated 1,2-(bis)trifluoromethylation o...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Guo, Shuo, AbuSalim, Deyaa I., Cook, Silas P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2019
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7065645/
https://ncbi.nlm.nih.gov/pubmed/31206968
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201905247
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