Llwytho...
Copper-mediated 1,2-bis(trifluoromethylation) of arynes
We herein describe an unprecedented 1,2-bis(trifluoromethylation) of arynes with [CuCF(3)] in the presence of an oxidant DDQ. The method allows the rapid construction of a new class of 1,2-bis(trifluoromethyl)arenes in one-step from aryne precursors under mild conditions. Its synthetic utility has b...
Wedi'i Gadw mewn:
| Cyhoeddwyd yn: | Chem Sci |
|---|---|
| Prif Awduron: | , |
| Fformat: | Artigo |
| Iaith: | Inglês |
| Cyhoeddwyd: |
Royal Society of Chemistry
2018
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| Pynciau: | |
| Mynediad Ar-lein: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6296300/ https://ncbi.nlm.nih.gov/pubmed/30627405 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc03754j |
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