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1,2-Bis(arylthio)arene synthesis via aryne intermediates

Lithium 1,1-diadamantylamide (LDAM) base-promoted insertion of arynes into disulfide S-S bonds is described. After generation of arynes from readily available aryl halides and triflates, reactions with diaryl and diisopropyl disulfides afford the insertion products in moderate to excellent yields. U...

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Detalhes bibliográficos
Publicado no:Chem Commun (Camb)
Main Authors: Mesgar, Milad, Nguyen-Le, Justin, Daugulis, Olafs
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6896799/
https://ncbi.nlm.nih.gov/pubmed/31328188
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc03863a
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