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1,2-Bis(arylthio)arene synthesis via aryne intermediates
Lithium 1,1-diadamantylamide (LDAM) base-promoted insertion of arynes into disulfide S-S bonds is described. After generation of arynes from readily available aryl halides and triflates, reactions with diaryl and diisopropyl disulfides afford the insertion products in moderate to excellent yields. U...
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| Udgivet i: | Chem Commun (Camb) |
|---|---|
| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6896799/ https://ncbi.nlm.nih.gov/pubmed/31328188 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9cc03863a |
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