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Silylaryl Halides Can Replace Triflates as Aryne Precursors

Silylaryl bromides and iodides can be prepared in one step from commercially available starting materials. Arynes can be generated from these compounds under conditions nearly identical to those employed for silylaryl triflates. Three distinct transformations, ortho-arylation of N-tritylanilines, in...

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Bibliographic Details
Published in:Org Lett
Main Authors: Mesgar, Milad, Daugulis, Olafs
Format: Artigo
Language:Inglês
Published: 2016
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5020908/
https://ncbi.nlm.nih.gov/pubmed/27415183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01952
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