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Silylaryl Halides Can Replace Triflates as Aryne Precursors

Silylaryl bromides and iodides can be prepared in one step from commercially available starting materials. Arynes can be generated from these compounds under conditions nearly identical to those employed for silylaryl triflates. Three distinct transformations, ortho-arylation of N-tritylanilines, in...

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Publicado en:Org Lett
Main Authors: Mesgar, Milad, Daugulis, Olafs
Formato: Artigo
Idioma:Inglês
Publicado: 2016
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5020908/
https://ncbi.nlm.nih.gov/pubmed/27415183
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.6b01952
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