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Aryl Carbamates: Mechanisms of Orthosodiations and Snieckus-Fries Rearrangements
Aryl carbamates are orthometalated by sodium diisopropylamide (NaDA) in THF. The resulting arylsodiums undergo Snieckus-Fries rearrangement to give orthoacylated phenols in good yield. The intermediate arylsodiums and resulting ortho-acylated phenolates are suggested to be monomeric. The rate-limiti...
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| Publicado no: | J Org Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7050188/ https://ncbi.nlm.nih.gov/pubmed/31257864 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.9b00968 |
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