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Mechanism of Phosphine-Catalyzed Novel Rearrangement of Vinylcyclopropylketone to Cycloheptenone: A DFT Study
[Image: see text] The title reaction is theoretically investigated in detail using density functional theory. Three possible routes starting from keto- or enol-type vinylcyclopropylketone are considered in this work. Results indicate that phosphine catalyst would first attack at the three-membered r...
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| Publicat a: | ACS Omega |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
American Chemical Society
2020
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| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7034002/ https://ncbi.nlm.nih.gov/pubmed/32095718 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acsomega.9b03902 |
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