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Phosphonate–Phosphinate Rearrangement
[Image: see text] LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH(3)O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–p...
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| Publicado no: | J Org Chem |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Chemical
Society
2014
|
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4301053/ https://ncbi.nlm.nih.gov/pubmed/25525945 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo502567j |
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