Ruthenium(II) Phosphine/Picolylamine Dichloride Complexes Hydrogenation and DFT Calculations

Treating [Ru(PPh<sub>3</sub>)<sub>3</sub>Cl<sub>2</sub>] with the amine 2-picolylamine (Picam) ligand in a 1:1 molar ratio, the Ru(II) complex <i>trans</i>-Ru(PPh<sub>3</sub>)<sub>2</sub>(Picam)Cl<sub>2</sub> (1) is...

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Main Authors: Manluan Sun, Sai Ge, Jianguo Zhao, Robert McDonald, Guibin Ma
Formato: Artigo
Idioma:Inglês
Publicado: MDPI AG 2022-03-01
Series:Catalysts
Assuntos:
hydrogenation
ruthenium complexes
hydrogen transfer mechanism
DFT calculation
Acceso en liña:https://www.mdpi.com/2073-4344/12/4/377
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