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Stereodivergent, chemoenzymatic synthesis of azaphilone natural products.
Selective access to a targeted isomer is often critical in the synthesis of biologically active molecules. Whereas small-molecule reagents and catalysts often act with anticipated site- and stereoselectivity, this predictability does not extend to enzymes. Further, the lack of access to catalysts th...
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| Published in: | J Am Chem Soc |
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| Main Authors: | , , , , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2019
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7029798/ https://ncbi.nlm.nih.gov/pubmed/31692339 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b09385 |
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