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Enantioselective total synthesis of the unnatural enantiomer of quinine
A practical enantioselective total synthesis of the unnatural (+)-quinine and (–)-9-epi-quinine enantiomers, which are important organocatalysts, is reported. The key transformation is a successive organocatalytic formal aza [3 + 3] cycloaddition/Strecker-type cyanation reaction to form an optically...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7020653/ https://ncbi.nlm.nih.gov/pubmed/32110303 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03879e |
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