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Enantioselective total synthesis of the unnatural enantiomer of quinine

A practical enantioselective total synthesis of the unnatural (+)-quinine and (–)-9-epi-quinine enantiomers, which are important organocatalysts, is reported. The key transformation is a successive organocatalytic formal aza [3 + 3] cycloaddition/Strecker-type cyanation reaction to form an optically...

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Publié dans:Chem Sci
Auteurs principaux: Shiomi, Shinya, Misaka, Remi, Kaneko, Mayu, Ishikawa, Hayato
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2019
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC7020653/
https://ncbi.nlm.nih.gov/pubmed/32110303
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03879e
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