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Electrochemical C–H bond activation via cationic iridium hydride pincer complexes
A C–H bond activation strategy based on electrochemical activation of a metal hydride is introduced. Electrochemical oxidation of ((tBu(4))PCP)IrH(4) ((tBu(4))PCP is [1,3-((t)Bu(2)PCH(2))-C(6)H(3)](–)) in the presence of pyridine derivatives generates cationic Ir hydride complexes of the type [((tBu...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7017868/ https://ncbi.nlm.nih.gov/pubmed/32110295 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc03076j |
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