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Decarbonylative ether dissection by iridium pincer complexes

A unique chain-rupturing transformation that converts an ether functionality into two hydrocarbyl units and carbon monoxide is reported, mediated by iridium(i) complexes supported by aminophenylphosphinite (NCOP) pincer ligands. The decarbonylation, which involves the cleavage of one C–C bond, one C...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Yoo, Changho, Dodge, Henry M., Farquhar, Alexandra H., Gardner, Kristen E., Miller, Alexander J. M.
Formato: Artigo
Idioma:Inglês
Publicado em: The Royal Society of Chemistry 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8162749/
https://ncbi.nlm.nih.gov/pubmed/34123222
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03736b
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