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Reversible addition of ethylene to a pincer-based boryl-iridium unit with the formation of a bridging ethylidene
This report examines reactions of a series of Ir complexes supported by the diarylboryl/bis(phosphine) PBP pincer ligand with ethylene: (PBP)IrH(4) (1), (PBP)IrH(2)(CO) (2), and (PBP)Ir(CO)(2) (3). The outcomes of these reactions differ from those typical for Ir complexes supported by other pincer l...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
The Royal Society of Chemistry
2020
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8162418/ https://ncbi.nlm.nih.gov/pubmed/34094348 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc04748a |
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