Room Temperature Acceptorless Alkane Dehydrogenation from Molecular σ-Alkane Complexes

[Image: see text] The non-oxidative catalytic dehydrogenation of light alkanes via C–H activation is a highly endothermic process that generally requires high temperatures and/or a sacrificial hydrogen acceptor to overcome unfavorable thermodynamics. This is complicated by alkanes being such poor li...

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Pubblicato in:J Am Chem Soc
Autori principali: McKay, Alasdair I., Bukvic, Alexander J., Tegner, Bengt E., Burnage, Arron L., Martínez-Martínez, Antonio J., Rees, Nicholas H., Macgregor, Stuart A., Weller, Andrew S.
Natura: Artigo
Lingua:Inglês
Pubblicazione: American Chemical Society 2019
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC7007236/
https://ncbi.nlm.nih.gov/pubmed/31246012
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b05577
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