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Proline-promoted dehydroxylation of α-ketols

A new single-step proline-potassium acetate promoted reductive dehydroxylation of α-ketols is reported. We introduce the unexplored reactivity of proline and, for the first time, reveal its ability to function as a reducing agent. The developed metal-free and open-flask operation generally results i...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Mostinski, Yelena, Lankri, David, Konovalov, Yana, Nataf, Riva, Tsvelikhovsky, Dmitry
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7006627/
https://ncbi.nlm.nih.gov/pubmed/32110298
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9sc02543j
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