A Highly Asymmetric Gold(III) η(3)‐Allyl Complex

A highly asymmetric Au(III) η(3)‐allyl complex has been generated by treating Au(η(1)‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf(2). The resulting η(3)‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature (1)H NMR sugge...

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Bibliographic Details
Published in:Angew Chem Int Ed Engl
Main Authors: Holmsen, Marte Sofie Martinsen, Nova, Ainara, Øien‐Ødegaard, Sigurd, Heyn, Richard H., Tilset, Mats
Format: Artigo
Language:Inglês
Published: John Wiley and Sons Inc. 2019
Subjects:
Communications
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC7003771/
https://ncbi.nlm.nih.gov/pubmed/31710154
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912315
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