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A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
A highly asymmetric Au(III) η(3)‐allyl complex has been generated by treating Au(η(1)‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf(2). The resulting η(3)‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature (1)H NMR sugge...
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| 發表在: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
John Wiley and Sons Inc.
2019
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7003771/ https://ncbi.nlm.nih.gov/pubmed/31710154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201912315 |
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