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Enantioselective catalytic synthesis of α-aryl-α-SCF(3)-β(2,2)-amino acids†
We herein report a novel entry towards chiral α-SCF(3)-β(2,2)-amino acids by carrying out the ammonium salt-catalyzed α-trifluoromethylthiolation of isoxazolidin-5-ones. This approach allowed for high enantioselectivities and high yields and the obtained heterocycles proved to be versatile platforms...
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| Publicado no: | Org Biomol Chem |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC6989214/ https://ncbi.nlm.nih.gov/pubmed/31915785 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c9ob02666e |
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